Nature often offers promising inspiration for biomimetic man-made materials. In a new report now published in Advanced Science, Faheng Wang and a team of scientists in advanced materials, engineering and science in China developed new cement materials based on unidirectionally porous architectures to replicate the designs of natural wood. The resulting wood-like cement material showed higher strength at equal densities, alongside multifunctional properties for effective thermal insulation, water permeability and easy adjustment for water repulsion. The team simultaneously achieved high strength and multifunctionality to make the wood-like cement a promising new building material for wood-mimetic designs with high performance. They presented a simple fabrication procedure to promote better efficiency during mass production with applications suited across other material systems.
Developing bioinspired wood-like materials
Porous cement-based materials possess low thermal conductivity for heat insulation, high sound-absorbing efficiency, outstanding permeability for air and water, while maintaining light weight and fire resistance. However, it still remains a key challenge to achieve the simultaneous enhancement of both mechanical and multifunctional properties including mechanical support, effective transport and good thermal insulation. It is therefore highly desirable to generate materials with enhanced mechanical and multifunctional properties to actively implement the design principles of natural wood. During the experiments, Wang et al. developed wood-like cement with unidirectionally porous architectures formed via a bidirectional freezing treatment method. The process allowed bridges to form between the constituents of the structure, the team then thawed the fully frozen bodies until the ice gradually melted and the cement hardened. The subsequent hydration process produced new minerals and gels within the cement, including hexagon-shaped calcium hydroxide, needle‐like ettringite and calcium-silicate-hydrate gels. The phases mainly originated at the cement lamellae and grew into their spacing during the thawing and curing process for better structural integrity with enhanced lamellae interconnections during porous cement formation. Using X-ray tomography (XRT), the team then revealed the formation of unidirectional micropores in the ice-templated cement.
Understanding the microstructure
Wang et al. used scanning electron microscopy (SEM) images to reveal the unidirectional pores between lamellae in the ice-templated cement that encompassed a large amount of interconnections bridging the lamellae. The team classified the interconnections into three types: (1) bridges and intersections formed due to cement particles engulfed in ice crystals during the process of freezing, (2) hexagon-shaped calcium hydroxide, and (3) needle-like ettringite. The latter minerals resulted from hydration reactions of cement during the thawing and curing processes. The cement lamellae contained abundant pores formed during the cement drying process due to the dehydration of gels and the removal of water. The scientists classified the pores within wood-like cement into three types, including (1) interlamellar open pores, (2) intralamellar open pores and (3) intralamellar closed pores. The interlamellar porosity was principally governed by the water content, which played a role as a pore-forming agent.
The mechanical and multifunctional properties of the material
The team obtained representative compressive stress-strain curves of the wood-like cement with or without silicon fume additions to its constitution. The compressive strength decreased monotonically with the rising water/cement ratios in the slurries used to develop the material, which eventually led to increased porosity in the cement. Since the failure strain of the material increased with increased total porosity, the strength of porous solids could be determined by its porosity. The team next measured the thermal conductivity coefficient of ice-templated, wood-like cement to show decreasing thermal conductivity with increasing porosity of the material. They also used infrared (IR) images to clearly observe the robust thermal insulation properties of the ice-templated cement material. To regulate the thermal insulation efficiency, Wang et al. adjusted the solid load in the cementitious slurries by increasing the water/cement content. The resulting cement material absorbed water due to the hydrophilic (water attractive) character of its internal surfaces. In contrast, they could prevent water penetrating the pores by waterproofing the surfaces with an organosilicon agent; such efforts on hydrophobicity could even cause the material to float on water. The method can therefore facilitate switchable applications as pervious or waterproof structures suited as building-materials.
Outlook for wood-like cement materials
In this way, Faheng Wang and colleagues presented an ice-templating technique as a viable approach to create unidirectional micropores for applications across ceramics, polymers, metals and their composites. The scientists developed a freeze-drying treatment process based on the self-hardening behavior of cement when in contact with hydration reactions. The resulting wood-like cement architecture contained a variety of pores in either open or closed forms and an abundance of interconnections bridging their lamellae. When the porosity increased, the strength of the cement decreased. The wood-like cement also featured lower thermal conductivity and good water permeability. The team could switch the cement material to be either water-repulsive or water-attractive via hydrophobic or hydrophilic treatment, respectively. The simple and practical materials development strategy coupled to the self-hardening nature of its constituents can significantly improve the time- and cost-effectiveness of the ice-templating technique to form sustainable concrete with potential to translate the method across to other material systems.
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Wang F. et al. Wood‐Inspired Cement with High Strength and Multifunctionality, Advanced Science, doi: doi.org/10.1002/advs.202000096
Monteiro P. et al. Towards sustainable concrete, Nature Materials, doi.org/10.1038/nmat4930
Roy D. M. New Strong Cement Materials: Chemically Bonded Ceramics, Science, 10.1126/science.235.4789.651
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Wood-inspired cement with high strength and multifunctionality (2021, January 5)
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